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Tilt, Polarity and spontaneous symmetry breaking in liquid crystals

May 9th, 2010

A. G. Vanakaras, D.J. Photinos and E. T. Samulski, Phys. Rev. E, 57(5), R4875-R4878 (1998).

Abstract: We show through explicit molecular modeling how tilt may be induced in layered mesophases and propagate across the-layers, using a concrete representation of flexible tail-core-tail calamitic mesogens in conjunction with-the variational cluster expansion. The results demonstrate that spontaneous symmetry breaking observed in smectic-liquid crystals-the tilt of the director relative to the layers-can be induced by excluded. volume interactions, both in the synclinic and in the anticlinic configurations.

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